Urea-methanal polymerisation

Read our standard health & safety guidance

Lesson organisation

This is a teacher demonstration, taking about 5 minutes for one polymerisation experiment. Extensions to show production of moulded articles will take longer. It should be performed in a fume cupboard or hood to avoid exposure to methanal vapour.

Apparatus and Chemicals

The teacher will need:

Eye protection: goggles
Disposable nitrile gloves (for handling the polymer)
Access to a fume cupboard visible to the class

Measuring cylinder, 100 cm³.
Throw-away containers with secure lids, at least 2 (see note 1)
Dropping pipette
Glass stirring rod
Object of simple shape for making suitable mould (see note 2)
Bunsen burner (optional).
Tongs (optional)

Quantities for one demonstration:

Methanal solution (formalin), 37 - 40%, (Toxic), 20 cm³ (see note 3)
Urea (carbamide)(Low hazard), 10 g
Sulfuric acid, concentrated (Corrosive), 1 cm³ (see note 4)
Plasticene
Aluminium foil

Technical notes

Methanal solution (Toxic) Refer to CLEAPSS Hazcard 63
Concentrated sulfuric acid (Corrosive) Refer to CLEAPSS Hazcard 98A
Urea (Low hazard) Refer to CLEAPSS Hazcard 35

1 The container used should be transparent (so the demonstration can be seen), disposable, and preferably should have a secure lid. Used 100 g coffee jars with screw tops are ideal, but any similar size glass or plastic container will do.

2 A mould for casting copies of an object can be made by pressing the object into Plasticene. The object selected should have a simple external shape. Enough Plasticene should be provided to press the shape into, forming a sufficiently substantial mould to retain its shape when handled.

3 Methanal solution (also known as formaldehyde solution, or formalin) should be in good condition. Because the vapour is unpleasant as well as toxic, the supply of this solution for this demonstration should be kept in the fume cupboard, in a stoppered bottle.

4 The acid used should be sulfuric acid, and NOT hydrochloric acid, because of the possibility of forming the carcinogen, bis-chloromethylether.

5 After the demonstration, dispose of the sealed container with the polymer inside as solid waste.

Procedure

HEALTH & SAFETY: Work in a fume cupboard and wear goggles. Wear gloves.when handling the polymer.

a Dissolve 10 g of urea in 20 cm³ of methanal solution in the disposable container.

b Add about 1 cm³ of concentrated sulfuric acid a drop at a time, using a dropping pipette, and stir steadily. Within a minute the solution begins to go milky and eventually a hard, white solid is formed which is difficult to remove from the container. A lot of heat is evolved.

c Show that the polymer is hard by poking the material with a spatula.

d Wash the polymer thoroughly before passing around the class, as it is likely to be contaminated with unreacted starting materials. Alternatively, pass it round in the container with the lid screwed on.

e Make a plasticene mould from the simple shape and line it with aluminium foil.

f Make another urea-methanal solution as above, but, immediately after adding the acid, pour some of the solution into the mould and allow it to polymerise. Remove from the mould when solid.

g Hold a sample of the polymer (from the mould) with tongs and heat in a Bunsen flame. It will char but not melt, showing that it is a thermosetting polymer.

Teaching notes

The reaction is a condensation polymerisation in which water is eliminated as the hydrogen atoms from the ends of one amino-group from each of two urea molecules combine with the oxygen atom from a methanal molecule. The remaining –CH₂– group from the methanal molecule then forms a bridge between two neighbouring urea molecules, as shown below. This process, repeated many thousands of times, forms long chains of urea and methanal molecules linked in this way.

Sometimes the second hydrogen atom on an amino-group will also react with a methanal molecule, producing a branch in the chain, and chains may even become cross-linked to each other. Eventually a random three-dimensional network of cross-linked chains is formed, giving a rigid structure and thus a hard, inflexible material.

The product has many cross links:

Because the tangle of cross-linked chains is almost impossible to separate, the material does not melt on heating, although it will eventually break down at high temperature, decomposing and giving off small molecules such as steam and nitrogen, leaving a charred mass which is largely carbon.

Health & Safety checked, August 2008